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Chemodex
2-Iodoso-3,4,5,6-tetrafluorobenzoic acid
Specifications / Handling
| Product Details | |
|---|---|
| Synonyms | FIBA Tetrafluoro-IBA; 4,5,6,7-Tetrafluoro-1-hydroxy-1,2-benziodoxole-3(1H)-one |
| Product Type | Chemical |
| Properties | |
| Formula | C7HF4IO3 |
| MW | 335.98 |
| CAS | 954373-94-5 |
| Source/Host Chemicals | Synthetic |
| Purity Chemicals | ≥95% (T) |
| Appearance | White crystalline. |
| Solubility | Soluble in DMSO. |
| Identity | Determined by NMR. |
| Declaration | Manufactured by Chemodex. |
| Other Product Data |
Click here for Original Manufacturer Product Datasheet |
| InChi Key | ZJHDTMPJHPTADJ-UHFFFAOYSA-N |
| Smiles | O[I]1OC(=O)C2=C(F)C(F)=C(F)C(F)=C12 |
| Shipping and Handling | |
| Shipping | AMBIENT |
| Short Term Storage | +4°C |
| Long Term Storage | -20°C |
| Handling Advice |
Keep cool and dry. Protect from light and moisture. |
| Use/Stability | Stable for at least 2 years after receipt when stored at -20°C. |
| Documents | |
| Safety Data Sheet |
Download PDF |
| Product Specification Sheet | |
| Datasheet |
Download PDF |
Scientific Background Information
Hypervalent iodine reagents. Convenient substitute of o-Iodosobenzoic acid (IBA) as an oxidant. Can be used for installations of α/β-unsaturation to carbonyl compounds, oxidations and cyclizations by single-electron transfer processes. Promotes faster reactions than IBA with better solubility in common organic solvents. An attractive feature is the ability to directly measure reactivity by 19F NMR spectroscopy without the use of deuterated solvents.
(1) R. Richardson, et al.; Angew. Chem. Int. Ed. 46, 6529 (2007)
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