AdipoGen Life Sciences

L-(-)-Camphoric acid

CHF 100.00
In stock
AG-CN2-0456-M500500 mgCHF 100.00
AG-CN2-0456-G0011 gCHF 160.00
AG-CN2-0456-GG252.5 gCHF 320.00
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Product Details
Synonyms (1S,3R)-Camphoric acid; (1S,3R)-1,2,2-Trimethyl-1,3-cyclo-pentanedicarboxylic acid
Product Type Chemical
Properties
Formula

C10H16O4

MW 200.2
Merck Index 14: 1733
CAS 560-09-8
Source/Host Chemicals Semi-synthetic.
Purity Chemicals ≥98% (HPLC)
Appearance White powder.
Solubility Soluble in ethanol, methanol or water.
Identity Determined by 1H-NMR and 13C-NMR.
Other Product Data

Optical Rotation: [α]20/D c=10 in EtOH: -48°±2.0°

InChi Key LSPHULWDVZXLIL-QUBYGPBYSA-N
Smiles CC1(C)C(CC[C@]1(C)C(O)=O)C(O)=O
Shipping and Handling
Shipping AMBIENT
Short Term Storage +4°C
Long Term Storage -20°C
Handling Advice Keep cool and dry.
Use/Stability Stable for at least 2 years after receipt when stored at -20°C.
Documents
MSDS Download PDF
Product Specification Sheet
Datasheet Download PDF
Description
  • Chirality inducing agent.
  • Useful tool as resolving agent to separate the isomers and purify racemic mixtures (e.g. DL-lysine) by fractionally crystallizing the product to obtain the pure isomer (e.g. D-lysine).
  • Can also be used as building block.
Product References
  1. Die Konstitution des Kamphers und seiner wichtigsten Derivate: O. Aschan, Verlag Friedrich Vieweg & Sohn (1903)
  2. The resolution of dl-lysine: C. P. Berg; J. Biol. Chem. 115, 15 (1936)
  3. Spontaneous resolution to absolute chiral induction: pseudo-Kagome type homochiral Zn(II)/Co(II) coordination polymers with achiral precursors: K.K. Bisht & E. Suresh; JACS 135, 15690 (2013)
  4. Binary co-crystals of the active pharmaceutical ingredient 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene and camphoric acid: K.K. Bisht, et al.; Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 70, 63 (2014)
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